Actually, it will sort of work to a degree (no pun intended.) Depending on how long the duct run is to the main cabin, it will increase the air pressure only slightly. You must be careful however, to not cut the flow off too much. If you do, then you will change the air-flow ratio over the evaporator coil and that may cause coil freeze up problems. Imo, I would experiment with the adjustable vent that you plan to install and monitor the evap. coil until you are sure that it’s not freezing. If it does start to freeze, turn the fan speed to a higher setting or open the aft cabin vent a bit more. If you don’t notice an increase in air velocity in the main cabin. You might try to install a damper at the a/c units plenum. This is where the two discharge hoses that form the ducts are. This will reduce the air flow to the aft cabin and boost the pressure to the main cabin without cutting down the flow across the coil. Make sure your filters are clean.